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Introduction
The emergence of three-dimensional (3D) printing technology has revolutionized the manufacturing industry by enabling the fabrication of complex structures with high precision and efficiency. Shape memory polymers (SMPs) are a class of smart materials that have gained significant attention due to their ability to change shape in response to external stimuli. The combination of 3D printing and SMPs offers a unique opportunity to develop advanced functional materials with tailored properties for various applications such as biomedical devices, aerospace components, and soft robotics.

This thesis aims to explore the potential of 3D printing for fabricating shape memory polymers and investigate the mechanical, thermal, and shape-memory properties of the printed structures. The study will also focus on optimizing the printing parameters to enhance the performance of the SMPs and expand their application range. Additionally, the thesis will investigate the process-structure-property relationships of 3D printed SMPs to provide insights for future research and development in this field.

Chapter 1: Introduction
1.1 Introduction
1.2 Background of study
1.3 Problem Statement
1.4 Objective of study
1.5 Limitation of study
1.6 Scope of study
1.7 Significance of study
1.8 Structure of the Thesis
1.9 Definition of Terms

Chapter 2: Literature Review
2.1 Overview of 3D printing technology
2.2 Shape memory polymers: properties and applications
2.3 Previous studies on 3D printing of SMPs
2.4 Additive manufacturing techniques for shape memory materials
2.5 Optimization of printing parameters for SMPs
2.6 Process-structure-property relationships in 3D printed SMPs
2.7 Challenges and opportunities in 3D printing of shape memory polymers
2.8 Future trends in the field of 3D printed SMPs
2.9 Comparison of traditional manufacturing methods with 3D printing
2.10 Summary of the literature review

Chapter 3: System Design and Methodology
3.1 Selection of shape memory polymer materials
3.2 Design of 3D printing process parameters
3.3 Characterization techniques for printed SMPs
3.4 Experimental setup for 3D printing of SMPs
3.5 Optimization of printing process for shape memory effects
3.6 Mechanical testing of printed SMPs
3.7 Thermal analysis of 3D printed SMPs
3.8 Microstructural analysis of printed samples

Chapter 4: System Implementation
4.1 3D printing of shape memory polymer samples
4.2 Evaluation of mechanical properties
4.3 Analysis of thermal behavior
4.4 Shape memory characterization
4.5 Comparison with traditional manufacturing methods
4.6 Case studies of 3D printed SMP applications
4.7 Discussion of results
4.8 Future directions for research and development

Chapter 5: Conclusion and Summary
5.1 Summary of key findings
5.2 Contributions to the field
5.3 Implications for future research
5.4 Recommendations for industry applications
5.5 Concluding remarks

Overall, this thesis will provide valuable insights into the potential of 3D printing technology for fabricating shape memory polymers, and the findings will contribute to the advancement of functional materials and additive manufacturing techniques. By investigating the process-structure-property relationships of 3D printed SMPs, this study aims to bridge the gap between research and practical applications in the field of smart materials.

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